Geology, geochemistry and isotope compositions of carbonate-hosted barite deposit in Koçaşlı (Gülnar-Mersin, Türkiye)

Main Article Content

Abstract

Due to the closure of the Neotethys ocean's branches, Precambrian-Mesozoic aged rocks are seen together along the Taurus Orogenic Belt. Significant barite deposits associated with carbonate rocks observed here. The Central Taurus Mountains' Devonian carbonates have evidence of the mineralization of Koçaşlı (Gülnar, Mersin) barite. The ore is oriented N10°W, with a slope and dip toward 60°SW. The ore zone is 7 meters thick and 15 meters long on average. Koçaşlı barite deposit is hosted in Paleozoic aged limestones in the Central Taurus Mountains.   In accordance with the results of the geochemical analysis, the BaO concentration of the ore samples ranges from 63.76% to 68.56%. Regarding geochemical characteristics, it is similar to sedimentary type deposits and has a low SrO content. The REE-poor ore zone has no significant trace element anomalies. Stable oxygen, sulfur, and 87Sr/86Sr isotopes were each used in sequence for the initial investigations of the barite in this region. In comparison to the isotope ratio of modern sea water, the 34S values of the Koçaşlı barite samples are quite high, indicating that they are enriched in the heavy isotope 34S. The amount of 18O isotope detected in barites is close to the amount of sulfates found in Devonian seawater. The barite samples utilized in this study have greater 87Sr/86Sr ratios than the isotopic composition of modern seawater. These 87Rb isotope levels for the barite sample indicate a significant input from the continental crust. Depending on the conclusions of the isotope analysis, sedimentary processes play an essential role in this region's mineralization.

Article Details

How to Cite
Karasu , V. ., Yalçın, C. . ., & Uras , Y. . (2023). Geology, geochemistry and isotope compositions of carbonate-hosted barite deposit in Koçaşlı (Gülnar-Mersin, Türkiye). Engineering Applications, 2(1), 75–83. Retrieved from https://publish.mersin.edu.tr/index.php/enap/article/view/852
Section
Articles

References

White, N. C., & Hedenquist, J. W. (1995). Epithermal gold deposits: styles, characteristics and exploration. SEG Discovery, (23), 1-13.

Wang, L., Qin, K. Z., Song, G. X., & Li, G. M. (2019). A review of intermediate sulfidation epithermal deposits and subclassification. Ore Geology Reviews, 107, 434-456.

Goldberg, E. D., & Arrhenius, G. O. S. (1958). Chemistry of Pacific pelagic sediments. Geochimica et cosmochimica acta, 13(2-3), 153-212.

Griffith, E. M., & Paytan, A. (2012). Barite in the ocean–occurrence, geochemistry and palaeoceanographic applications. Sedimentology, 59(6), 1817-1835.

Ketin, İ. (1966). Tectonic units of Anatolia (Asia minor). Bulletin of the Mineral Research and Exploration, 66, 23-34.

Şengör, A. C., & Yilmaz, Y. (1981). Tethyan evolution of Turkey: a plate tectonic approach. Tectonophysics, 75(3-4), 181-241.

Okay, A. I., & Tüysüz, O. (1999). Tethyan sutures of northern Turkey. Geological Society, London, Special Publications, 156(1), 475-515.

Richards, J. P. (2015). Tectonic, magmatic, and metallogenic evolution of the Tethyan orogen: From subduction to collision. Ore Geology Reviews, 70, 323-345.

Hanilçi, N., Öztürk, H., & Kasapçı, C. (2019). Carbonate-Hosted Pb-Zn Deposits of Turkey. Mineral Resources of Turkey, 497-533.

Özgül, N. (1976). Some geological aspects of the Taurus orogenic belt (Turkey), Bull Geol Soc Turk, 19, 65–78, (in Turkish with English abstract).

Özalp, S., & Demirkol, C. (2003). Orta Toroslar'da Büyükeceli (Gülnar)-Yeşilovacık (Silifke) dolayının tektono-stratigrafi birimleri. Geosound, (42), 73-96.

Yalçın, C., Karasu, V., & Uras, Y. (2022). Paleozoyik Yaşlı Kayaçlar ile İlişkili Koçaşlı (Gülnar, Mersin) Baritlerinin Jeolojik Özellikleri ve Akkuyu Nükleer Santrali ile İlişkisi, 1st International Conference on Engineering and Applied Natural Sciences (ICEANS, 2022), 922-926, May 10-13, 2022, Konya, Turkey.

Işık, V. (2016). Torosların Jeolojisi; Türkiye Jeolojisi Ders Notu. Ankara Üniversitesi, Jeoloji Mühendisliği Bölümü, Ankara.

Özgül, N., & Gedik, İ. (1973). New data on the stratigraphy and the conodont faunas of Çaltepe limestone and Seydişehir formation, Lower Paleozoic of Central Taurus Range, Bulletin of the Geological Society of Turkey, 16, 39-52.

Özgül, N., & Kozlu, H. (1993). Geology of an area between Kozan-Feke-Mansurlu, TPAO Report No: 3380. Ankara, (unpublished).

Ozgul, N.; Kozlu, H. (2002). Stratigraphy and findings related to structural location of Kozan-Feke (Dogu Toroslar) area. TPJD Bull, 14(1), 1-36.

Podufal, P. (1977). Die Dreislar Baryt-Gänge: Der Aufschluss, (55) Beiheft 2, 37-40.

Puchelt, H. (1967). Zur Geochemie des Bariums im exogenen Zyklus:Sitzungsber., Heid., Ak. Wiss., Math. Nat. Kl., Jg. (4) Abh., 205 s.

Scherp, A. (1974). Die Herkunft des Baryts in der Pyrit-Zinkblende-Baryt-Lagerstätte Meggen. N. Jb. Geol. Paläont., Mh., 38-53.

Ozdogan, A. T., Uras, Y., & Oner, F. (2017). Geochemistry of the barite deposits near Adana-Feke area (Eastern Taurides). Russian Geology and Geophysics, 58, 1351-1367.

Kusakabe, M., & Robinson, B. W. (1977). Oxygen and sulfur isotope equilibria in the BaSO4- HSO4− H2O system from 110 to 350° C and applications. Geochimica et Cosmochimica Acta, 41(8), 1033-1040.

Claypool, G. E., Holser, W. T., Kaplan, I. R., Sakai, H., & Zak, I. (1980). The age curves of sulfur and oxygen isotopes in marine sulfate and their mutual interpretation. Chemical geology, 28, 199-260.

Paytan, A., Mearon, S., Cobb, K., & Kastner, M. (2002). Origin of marine barite deposits: Sr and S isotope characterization. Geology, 30(8), 747-750.

Elderfield, H. (1986). Strontium isotope stratigraphy. Palaeogeography, palaeoclimatology, palaeoecology, 57(1), 71-90.

Monnin, C., & Cividini, D. (2006). The saturation state of the world’s ocean with respect to (Ba, Sr) SO4 solid solutions. Geochimica et Cosmochimica Acta, 70(13), 3290-3298.

Clark, S. H., Poole, F. G., & Wang, Z. (2004). Comparison of some sediment-hosted, stratiform barite deposits in China, the United States, and India. Ore Geology Reviews, 24(1-2), 85-101.

Cansu, Z., & Öztürk, H. (2020). Formation and genesis of Paleozoic sediment-hosted barite deposits in Turkey. Ore Geology Reviews, 125, 103700.

Yalçın, C. (2022). Preliminary Datas of Carbonate-rock hosted barite Mineralization in Dadağlı (Kahramanmaraş) area, Turkey. Advanced Engineering Days (AED), 2, 33-35.

Yalçın, C. (2022). Geochemical and geological approach to the carbonate-hosted barite deposits in Dadağlı (Kahramanmaraş), Turkey. Engineering Applications, 1(1), 55-62.

Karasu, V., Yalçın, C., & Uras, Y. (2022). Isotope geochemistry of Koçaşlı Barite mineralization. Advanced Engineering Days (AED), 5, 178-180.